小分子有机电致发光器件和材料的研究及应用

有机电致发光器件(OLED)是在电场作用下,以有机材料为活性发光层的器件.由于OLED具有亮度高、响应快、视角宽、工艺简单、可柔性等优点,在现代科学研究及技术应用中备受关注.其商业化应用,诸如平板显示(FPD)和固体照明(SSL)等,正在不断向前推进.本文综述了小分子OLED的各种器件结构和功能材料研究进展以及该领域存...     

带有负顾客的M/M/c多重工作休假排队

考虑服务台在休假期间不是完全停止工作,而是以相对于正常服务期低些的服务率服务顾客的M/M/c工作休假排队模型.在此模型基础上,针对现实的M/M/c排队模型中可能出现的外来干扰因素,提出了带有负顾客的M/M/c工作休假排队这一新的模型.服务规则为先到先服务.工作休假策略为空竭服务异步多重工作休假.抵消原则为负顾客一对一抵消处于正常服务期的正顾客,若系统中无处于正常服务期的正顾客时,到达的负顾客自动消失,负顾客不接受服务.首先,由该多重休假模型得到其拟生灭过程及生成元矩阵,然后运用矩阵几何方法给出系统队长的稳态分布表达式和若干系统指标.     

Direct Determination of Paracetamol in Environmental Samples Using Screen‐printed Carbon/Carbon Nanofibers Sensor – Experimental and Theoretical Studies

The paper describes the first electrochemical method (differential pulse adsorptive stripping voltammetry, DPAdSV) using a screen‐printed sensor with a carbon/carbon nanofibers working electrode (SPCE/CNFs) for the direct determination of low (real) concentrations of paracetamol (PA) in environmental water samples. By applying this sensor together with DPAdSV, two linear PA concentration ranges from 2.0×10^?9 to 5.0×10^?8 mol L^?1 (r=0.9991) and 1.0×10^?7–2.0×10^?6 mol L^?1 ( r=0.9994) were obtained. For the accumulation time of 90 s, the limit of detection was 5.4×10^?10 mol L^?1. Moreover, the SPCE/CNFs sensor and the DPADSV procedure for PA determination are potentially applicable in field analysis. The process of PA adsorption at the SPCE/CNFs surface was investigated by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and theoretical studies. In the theoretical study of the interaction of CNF and PA, the first species was modelled by graphene‐like clusters containing up to 37 rings. It was found that the preferable orientation of PA is parallel to the carbon surface with the binding energy of about ?68 kJ/mol calculated by symmetry‐adapted perturbation theory (SAPT). Both the selectivity and the accuracy of the developed sensor for real sample analysis were also investigated using Polish river and sea samples.     

新型涡旋多相泵原理及其工作过程研究

提出了一种新型涡旋式气液多相混输泵,通过构建变啮合间隙涡旋齿型线,使得所形成的压缩腔存在一条通向排出口的内泄漏卸压通道。构建了一种液相压缩卸荷的新方法,解决了容积式多相泵在混输较高含液率介质时易出现的压缩腔液击问题。介绍了新型涡旋多相泵的工作原理,得到了变啮合间隙涡旋齿型线的生成方法和型线方程,分析了工作腔容积和啮合间隙的变化规律。建立了涡旋多相泵工作过程中气液介质在伴有内泄漏时的增压过程热力模型,求解得到了工作过程中压力的变化规律。     

具有不耐烦顾客和多重工作休假的排队库存系统

研究具有不耐烦顾客和多重工作休假的M/M/1/N排队库存系统模型,分别考虑了系统中库存为零时服务员休假和系统中顾客数为零时服务员休假两种休假方式,基于(s,S)库存策略,运用矩阵迭代方法得到了系统稳态概率分布,并给出系统相关性能指标,进而建立系统平均库存费用函数.通过数值算例对比分析了两种休假方式下的系统主要参数变化对系统重要性能指标的影响,并在最优费用的层面对两个模型的优劣进行了对比分析.     

透平级非设计工况气动性能的数值模拟

采用新型 ＬＵ隐式格式和改良型高阶 ＭＵＳＣＬ ＴＶＤ格式求解全三维雷诺平均的 Ｎａｖｉｅｒ－Ｓｔｏｋｅｓ方程和 ｑ－ｗ低雷诺数双方程湍流模型,对一台ＮＡＳＡ跨音单级透平在不同工况下的内部流场进行了详细的数值模拟,并与可能得到的实验结果进行了对比。总结了小流量工况下动叶内部流动的分离模式。     

新型等离子体喷射触发气体开关

为了提高气体开关的同步性,降低自放电概率和抖动,提出并设计了一种新型等离子体喷射触发气体开关。开关整体结构与传统的三电极场畸变开关相似,最大特点是在触发电极内部嵌入一个微型激励腔,用于产生等离子体喷射。研究了触发电压和气压对等离子体的喷射特性的影响,对比场畸变和等离子体喷射两种触发方式下开关触发特性的差异,并研究触发电压对开关性能的影响。实验结果表明:等离子体喷射高度随触发电压的升高而增加,随气压的升高而降低;采用等离子体喷射触发能够显著降低过压间隙的延时和抖动;提高触发电压不但降低开关的抖动,而且还扩展开关稳定触发的工作范围;当触发电压80kV,工作系数27.4%,开关仍然能够可靠触发,延时和抖动分别为97.1ns和3.5ns。     

Stabilization of betatron tune in Indus-2 storage ring

Indus-2 is a synchrotron radiation source that is operational at RRCAT, Indore, India. It is essentially pertinent in any synchrotron radiation facility to store the electron beam without beam loss. During the day to day operation of Indus-2 storage ring, difficulty was being faced in accumulating higher beam current. After examination, it was found that the working point was shifting from its desired value during accumulation. For smooth beam accumulation, a fixed desired tune in both horizontal and vertical plane plays a significant role in avoiding beam loss via the resonance process. This required a betatron tune feedback system to be put in the storage ring. After putting ON this feedback, the beam accumulation was smooth. The details of this feedback and its working principle are described in this paper.     

Gaining effciency via weighted estimators for mul-tivariate failure time data

Multivariate failure time data arise frequently in survival analysis.A commonly used tech-nique is the working independence estimator for marginal hazard models.Two natural questions are how to improve the effciency of the working independence estimator and how to identify the situations under which such an estimator has high statistical effciency.In this paper,three weighted estimators are proposed based on three different optimal criteria in terms of the asymptotic covariance of weighted estimators.Simpli...     

ΔF氧传感器的性能及其正确使用和常见故障排除

介绍ΔF氧传感器的工作原理,高纯气体中痕量氧测定方法的性能比较,着重介绍ΔF氧传感器的正确使用、维护和常见故障的排除。